Number of options = number of doors (not number of different outcomes).
Three doors means 3 options (not 2) and 33% chance of choosing correctly the first time and 67% chance of choosing correctly if you switch after all but two doors are opened.
100 doors means 100 options (not 2) and 1% chance of choosing correctly the first time and 99% chance of choosing correctly if you switch after all but two doors are opened.
In neither case does one have a 50% chance.
The only person who has a 50% chance is the casual bystander who enters the stage when only two doors remain shut with no idea which door the contestant original chose (hereinafter referred as the "new entrant").
When all doors are shut, the odds of picking the correct door = 1/n, where n = the number of doors.
But if you come in after the dud doors have been opened and do not know which door the contestant picked, the probability of your guessing the correct door is 50%.
However, if the new entrant finds out which door the contestant picked they should choose the other doors as the probability that the other door is the right one is inversely proportionate to the probability the contestant chose right, ie:
Contestant's probability of being right first time is:
1/n
ie 1/3 or 1/100 where number of doors (n) is 3 or 100, respectively.
Knowing this, the new entrant picks the opposite to the contestant as the odds of that door being right are:
n-1/n
ie (3-1)/3 (67%) or (100-1)/100 (99%) where n = 3 or 100, respectively.
If they are alive to this, the contestant switches too and shares the same probability as the new entrant whose probability is higher by a factor of n-1
ie 3-2 (2 times higher) or (100-1) (99 times higher) where n = 3 or 100, respectively.
Opening dud doors does not alter the probability that the initial selection will be correct. And so the door that remains must have probability 1-(1/n), or 67% or 99% where n = 3 and 100, respectively.
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