Mate, if they're off a Mk1 TT (not the current shape) then they will bolt straight on, no spacers or adapters needed. If you have ball seated wheel bolts, these should be fine too. Is easy to check this, have a look at the top of the thread where it meets the bolt head and it will either be conical in shape or a ball.
Wheel bolt torque is specified as 120Nm for a Golf.
Shouldn't need an alignment after removing wheels as you are not altering suspension geometry, just make sure the wheels are balanced....
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