The biggest thing it will do is to cool the charge. Unless you have a temp sensor that then injects a bit more fuel via a computer controlled ECU, it's going to do very little. On an older diesel you can then adjust it to add more fuel, but when the water runs out, it's going to blow smoke as it's now too rich. You need a way of factoring that in. Also, as Tim mentioned, you need to have a very high pressure pump and specific nozzle to really atomise the water, a squirty bottle is a ways off that, but give it a go in moderation.
The downside is that water then displaces oxygen, and you have less in the chamber to combust, so it's kind of a catch 22, more in there because it's more dense, yet the water itself is displacing oxygen.
Bottom line if you add some Methanol in a 50/50 mix, suddenly you have an extra fuel source that won't ignite till the diesel does, and this will generally liberates more power.
In a non intercooled diesel it would be a great move. It's definately something I'm going to have a go at, with a specific diesel setup.
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