I have had my V6 Passat for 3 years now, just clicked over 107,000Km still love driving it.
These cars are pretty rare to get with all the options, took me over 2 years to find one with the drivers assistance package (for the HIDs) and the rest of the bells and whistles; Although I am very picky about my cars.
Things to look out for,
60,000k service, make sure the Haldex and DSG service was done.
Pre 2011, check for timing chain noise on cold startup.
Brakes via the dealer cost a lot, 3rd party is much better (DBA rotors).
Check the car via VCDS or a ODB scanner if you can for any stored codes.
mid 2011 - early 2012 cars don't have rear view cameras, due to Sony running out of stock after the Tsunami in Japan.
A bit of gearbox whine in 4th is normal on the AWD Passats including the R36
If you have any other questions let me know.
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