Next, check the voltage and ground at the sunroof controller \ motor.
Here is what it looks like.
2012-2014 VOLKSWAGEN PASSAT B7 SEDAN UPPER SLIDING ROOF SUNROOF GLASS MOTOR OEM | eBay
And here is where it's located, Red 12v, brown Gnd
Removing And Installing Sliding Sunroof Motor - Volkswagen Passat 2011 Workshop Manual [Page 245] | ManualsLib
If you have voltage at that connector, it would most likely be the controller that's built into the motor; other tests to confirm need more advanced tools than just a multimeter.
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