The main concern about ending up in McLaren Vale is that people still need to get back, so if we make it 120km+ to get there, that may push it over the line for some people, whereas a start and finish near the city is a bit more accessible. Having said that, I'm happy to go further. What do people think?
Here's an alternative route, that takes in the roads you and Rhys mentioned, and ends up in McLaren Vale at Blessed Cheese (a fantastic cafe and lunch spot):
Option 2: http://goo.gl/maps/rjhxN
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