Whilst you might not expect an O2 sensor to fail at 100K, I had an O2 sensor before the cat fail on my 3.2L V6 at 65K. It failed due to signal circuit shorted to heater circuit. It's very easy to replace the wrong side and I replaced both left and right. My car is an 2006 build so you'd think VW would have figured out how to build quality O2 sensors by 2012.
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