When I was up in Coffs Harbour last, I drove a family friend's Passat 125TDI wagon and compared it to my RS TFSI. TBH I didn't really hear that much of a difference, maybe because the Passat was a diesel. If I were one to do many highway kms road-noise would be a thing to me, but otherwise not really, and it's not like the Skoda is that much worse than the Passat (and as someone mentioned, the Octavia is equivalent to the Jetta - VW acquired the Skoda NVH package for the Jetta after the Octavia was launched).
On the RS vs normal Octavias, I bought mine when the RS was petrol-only, but I can tell you that it is nosier because the exhaust is bigger and the tyre package is too. Otherwise it isn't.
RE Octavia vs Passat, I'd definitely go for the Octavia. Not because I already own one, but because I see the Octavia as much better value (even though the used Passat you might find is optioned up), and you can possibly option-up the Octavia (or if it's an RS...) to a price that the Passat will be. Otherwise the quality, space, reliability, preformance/handling and running costs are pretty much the same. I also like new car smell
Mine: Silver 2006 Volkswagen Golf Sportline 2.0FSI 6M (with a sunroof)
Parents': Candy White 2008 Skoda Octavia RS 2.0TFSI 6M Liftback
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