I'd put the isolator as close to the original battery as possible (reduce the chance of a short), and keep the cables inside - they are too easy to damage if underneath your van.
Also, seeing as you are putting the battery inside the cabin, please make sure you get one that is safe for interior use (ie gel or AGM), as the std "wet" lead acid batteries are too dangerous to have inside with people.
2017 MY18 Golf R 7.5 Wolfsburg wagon (boring white) delivered 21 Sep 2017, 2008 Octavia vRS wagon 2.0 TFSI 6M (bright yellow), 2006 T5 Transporter van 2.5 TDI 6M (gone but not forgotten).
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