The car should have a sticker in the fuel flap that lists the manufacturer's recommended inflation pressures.
There's no pressing need to deviate from the manufacturer's instructions or specifications unless you wish to alter the car's dynamic behaviour.
The figures listed on the sticker are for "cold" tyres (i.e. tyres that are have been stationary for a few hours and at ambient temperature).
If inflating the tyres while they're warm, you should add an extra 2-4 psi to compensate, depending on how far or long they've been driven on.
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