It's very possible that the pinging was due to 'old' fuel. So it's good that you have put a full tank of BP Ultimate in there. I wouldn't worry if it goes away.
As for the 'rusting' of the brakes. It'll happen even only a few hours after you've washed the car. Don't worry too much about it - after a few brake applications it goes away.
I would DEFINITELY be asking them to change the oil and filter though.... actually ask for an entire service for free. The service schedule is 15,000km OR 12 months. They've sold you the car 12 months old, so it's due for a service now.
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